Free-radical addition of phenyl- and diphenylphosphines to 2-vinyl-1,3-dioxa-6-aza-2-silacyclooctanes |
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| Authors: | M G Voronkov N M Kudyakov V I Rakhlin A L Kuznetsov M V Sigalov R G Mirskov |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions Phenyl- and diphenylphosphines add to 2,6-dimethyl-2-vinyl-1,3-dioxa-6-aza-2-silacyclooctane upon the action of UV irradiation to form 2,6-dimethyl-2-(2-phenylphosphino)ethyl)]-1,3-dioxa-6-aza-2-silacyclooctane and 2,6-dimethyl-2-(2-diphenylphosphino)ethyl]-1,3-dioxa-6-aza-2-silacyclooctane, respectively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2615–2616, November, 1985. |
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