| 1,3-二苯基-5-吡唑啉酮三种异构体的结构及其发光性能 |
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| 引用本文： | 赵显梅,车圆圆,丁盛,刘浪.1,3-二苯基-5-吡唑啉酮三种异构体的结构及其发光性能[J].化学通报,2016,79(10):952-957,980. |
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| 作者姓名： | 赵显梅 车圆圆 丁盛 刘浪 |
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| 作者单位： | 新疆大学应用化学研究所,新疆大学应用化学研究所,新疆大学应用化学研究所 |
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| 基金项目： | 国家自然科学基金项目（21362037）;NSFC-新疆联合基金(U1303391) |
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| 摘 要： | 本文以1,3-二苯基-5-吡唑啉酮(DPP)为研究对象,采用不同溶剂对其进行重结晶,得到了3种不同颜色和不同构型的异构体。通过XRD粉末衍射、IR、1H NMR等确定了3种异构体的组成和结构,通过荧光光谱研究了它们的发光行为。结果表明这类化合物具有聚集诱导发光性能和光异构化性能,而且溶剂对产物的构型及发光性能均有明显的影响。此外,将该化合物与无规聚苯乙烯复合制备的薄膜也具有很好的荧光性能,在防伪领域具有潜在的应用。
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| 关 键 词： | 吡唑啉酮 重结晶 聚集诱导发光 异构体 薄膜 |
| 收稿时间： | 2016/2/27 0:00:00 |
| 修稿时间： | 2016/3/26 0:00:00 |
Structures and Emission Properties of Three Isomers on1, 3-Diphenyl-5-Pyrazolone |
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| Zhao Xianmei,Che Yuanyuan,Ding Sheng and Liu Lang.Structures and Emission Properties of Three Isomers on1, 3-Diphenyl-5-Pyrazolone[J].Chemistry,2016,79(10):952-957,980. |
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| Authors: | Zhao Xianmei Che Yuanyuan Ding Sheng and Liu Lang |
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| Abstract: | 1, 3-Diphenyl-5-pyrazolone (DPP) was recrystallized from three different solvents, three isomers with different color were obtained. Their composition and structures were characterized by IR, 1H NMR, X-ray powder diffraction analysis. Their emission behaviors were studied by fluorescence spectra. The results indicate that these isomers exhibit the aggregation-induced emission behavior and photoisomerization. Moreover, the solvent obviously affects the structures and fluorescence of products. In addition, composite film also exhibits the good fluorescence, which has potential application in the field of antifake. |
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| Keywords: | pyrazolone recrystallization aggregation-induced emission isomers film |
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