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Structural studies of lead aluminate glasses
Institution:1. Department of Physics, University of Warwick, Coventry CV4 7AL, UK;2. ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX, UK;3. Physics Department, Coe College, 1220 1st Avenue NE, Cedar Rapids IA 52402, USA
Abstract:Lead aluminate melts were quenched rapidly with a roller quencher and bulk glasses were formed over a composition range from 72.5 to 80.0 mol% PbO. Pulsed neutron diffraction, 27Al MAS NMR and Raman spectroscopy were used to study the structure of a series of these glasses. The results show that in the glasses the aluminium is four coordinated by oxygen across the compositional range, with a bond length of about 1.76 Å. The Pb–O peak in the neutron correlation function is asymmetric, and it can be modelled in terms of two bond lengths of ∼2.25 Å and ∼2.47 Å, with the majority of the coordination at the shorter distance. There is evidence that most or all of the lead ions are on asymmetric sites, coordinated by three oxygens in a trigonal pyramid arrangement. Both the neutron diffraction and Raman results indicate that the Pb–O bond lengths become shorter with increasing lead content.
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