Structural study of levitated liquid Y2O3 using neutron scattering |
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Affiliation: | 1. Institut Laue Langevin, ILL, 6 Rue Horowitz BP 156, 38042 Grenoble cedex 09, France;2. Centre de Recherche sur les Matériaux à Haute Température, CNRS-CRMHT, 1d Avenue de la Recherche Scientifique, 45071 Orléans cedex 2, France;3. CRMD, 1b Rue de la Férollerie, 45071 Orléans cedex 2, France |
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Abstract: | The local structure of liquid Y2O3 at 2800 K has been investigated by combining aerodynamic levitation and laser heating with the neutron scattering technique. Despite relatively low counting statistics, we have been able to determine the short-range order in the liquid. In particular, we found Y–O and Y–Y coordination numbers around 6 and 12, confirming our previous study by anomalous X-ray scattering. The unusually sharp main diffraction peak observed with X-ray measurements, and characteristic of a high degree of chemical ordering, is strongly reduced in the neutron structure factor and thus indicates that it is mostly due to Y–Y correlations. |
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