Thermodynamic properties and polymorphism of 1-alkyl-3-methylimidazolium bis(triflamides) |
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Institution: | Belarusian State University, Chemistry Faculty, 14 Leningradskaya Street, 220030 Minsk, Belarus |
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Abstract: | Heat capacities in a range of temperatures of (5 to 370) K, enthalpies and temperatures of phase transitions for 1-ethyl-3-methylimidazolium bis(triflamide) (C2mim]NTf2]) and 1-octyl-3-methylimidazolium bis(triflamide) (C8mim]NTf2]) have been determined by adiabatic calorimetry. C2mim]NTf2] has been found to form four crystalline phases with different fusion temperatures. Formation of the phases can be controlled by the temperature of annealing during crystallization. C8mim]NTf2] forms three sequences of crystalline modifications, each including two polymorphs. Based on results of the measurements, thermodynamic functions for the compounds under study have been calculated.A heat-capacity anomaly near T = 230 K reported earlier for C4mim]NTf2] and C6mim]NTf2] have been found in some crystalline modifications of both the studied compounds. The position of the anomaly depends on the temperature of annealing of the crystals. |
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