Chemical characteristics of Dy–S bonds in Ge–As–S glass |
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| Institution: | 1. Department of Materials Science and Engineering, Hankuk Aviation University, Goyang, Gyeonggi 412-791, Republic of Korea;2. Center for Information Materials and Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, Gyeongbuk 790-784, Republic of Korea;3. Bio-Nanotechnology Research Center, Korea Research Institute of Bioscience and Biotechnology, Daejeon 305-333, Republic of Korea |
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| Abstract: | From Dy L3-edge extended X-ray absorption fine structure spectroscopic analysis of Dy-doped Ge–As–S glass, we verified that both the coordination number and Dy–S distance are decreased in this representative chalcogenide glass compared to those in the Dy2S3 crystalline counterpart. The strong covalent nature inherent in chemical bonds between the constituent atoms of Ge–As–S glass would be responsible for the enhanced covalency of the Dy–S bonds, which would then be sensitively related to the optical characteristics of the 4f ↔ 4f transitions of Dy3+ as well as the low rare-earth solubility exhibited by the Ge–As–S glass. |
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