Determination of solvation and specific interaction enthalpies of adamantane derivatives in aprotic solvents |
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| Institution: | 1. Department of Chemical Engineering, Engineering Institute (ISEL), Polytechnic Institute of Lisbon, CQB, R. Conselheiro Emídio Navarro 1, 1950-062 Lisboa, Portugal;2. Department of Chemistry and Biochemistry, Faculty of Sciences, University of Lisbon, CQB, Ed. C8, Campo Grande 1749-016 Lisboa, Portugal |
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| Abstract: | Solution and solvation enthalpies at infinite dilution of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone are reported at 298.15 K in a set of 14 aprotic solvents. The specific interaction enthalpies of the solid solutes are calculated using a methodology recently published by other authors. 1-Adamantanol’s specific interaction enthalpies show a good correlation with the Kamlet–Taft β scale. |
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