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Structural studies on AsSe–AgI glasses
Affiliation:1. Institute of Electrochemistry and Energy Systems, G. Bonchev Str. Bl.10, 1113 Sofia, Bulgaria;2. University of Chemical Technology and Metallurgy, Department of Physics, 8Kl Ohridsky Blvd., 1756 Sofia, Bulgaria;3. Research Institute for Solid State Physics and Optics, P.O. Box 49, H-1525 Budapest, Hungary;4. Institute of Physics, Chemnitz University of Technology, D-09107 Chemnitz, Germany;5. Hamburger Synchrotronstrahlungslabor HASYLAB am Deutschen Elektronen-Synchrotron DESY Notkestrasse 85, D-22603 Hamburg, Germany;6. Laboratoire Léon Brillouin CEA-SACLAY, 91191 Gif sur Yvette cedex, France
Abstract:The atomic structure of the binary AsSe, ternary (AsSe)80Ag20, (AsSe)85I15 and quaternary (AsSe)65(AgI)35 glasses has been studied with the X-ray and neutron diffraction. The local order was also probed with the extended X-ray absorption fine structure spectroscopy at Ag, As and Se K-edges. All experimental data were modeled simultaneously by the reverse Monte Carlo technique. Analysis of the partial pair distribution functions and their characteristics enabled to retrace the structural changes from binary AsSe to pseudo-binary (AsSe)100−x(AgI)x system and to study the influence of Ag and I incorporation on the local structure.
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