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Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate,strontium nitrate,and manganese nitrate at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa
Institution:Department of Chemistry and Biochemistry, College of Physical and Mathematical Sciences, Brigham Young University, Provo, UT, 84602-5700, USA
Abstract:Apparent molar volumes V? and apparent molar heat capacities Cp,? were determined at the pressure 0.35 MPa for aqueous solutions of magnesium nitrate Mg(NO3)2 at molalities m = (0.02 to 1.0) mol · kg?1, strontium nitrate Sr(NO3)2 at m = (0.05 to 3.0) mol · kg?1, and manganese nitrate Mn(NO3)2 at m = (0.01 to 0.5) mol · kg?1. Our V? values were calculated from solution densities obtained at T = (278.15 to 368.15) K using a vibrating-tube densimeter, and our Cp,? values were calculated from solution heat capacities obtained at T = (278.15 to 393.15) K using a twin fixed-cell, differential, temperature-scanning calorimeter. Empirical functions of m and T were fitted to our results, and standard state partial molar volumes and heat capacities were obtained over the ranges of T investigated.
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