Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]

Authors:	Kelly Boutilier Leonard R MacGillivray S Subramanian Michael J Zaworotko

Institution:	(1) Department of Chemistry, Saint Mary's University, B3H 3C3 Halifax, Nova Scotia, Canada

Abstract:	The complex salt, 1-MeimH]₂cis-MoO₂(sal)₂], 1, (1-Meim=1-methylimidazole, sal=o-C₆H₄(C^–) (COC^–)) has been prepared by reacting Mo(CO)₆ with molten 1-methyl imidazolium salicylate 1-MeimH]salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P¯1,a=9.220(2),b=9.469(3),c=15.368(4)Å, =105.04(4),=99.48(3), =109.48(3)°,Z=2,D _calc=1.60 g/cm. 2809 reflections withI>2.5(I) gave a final values ofR=0.031 andR _w=0.041.

Keywords:
本文献已被 SpringerLink 等数据库收录！