Direct anodic oxidation ofp-methoxytoluene in methanol. The effect of electrolysis conditions |
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Authors: | Yu. N. Ogibin A. I. Ilovaisky V. M. Merkulova G. I. Nikishin |
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Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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Abstract: | The effect of anions of the supporting electrolyte (F–, dialkylphosphate, TsO–, and BF4– and other electrolysis conditions (anode material, temperature, substrate concentration) on the selectivity of the direct anodic oxidation ofp-methoxytoluene in methanol into 4-methoxybenzaldehyde dimethylacetal was studied. The highest selectivity was obtained in the presence of fluoride anion.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 524–527, March, 1995.This work was financially supported by the Ministry of Science, High School and Technical Policy of the Russian Federation within the scope of the State scientific-technical program Ecologically harmless processes of chemistry and chemical technology (project No. 1.140 Low-tonnage chemical products) and by the International Science Foundation (Grant Ch-2-1246-0923). |
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Keywords: | anodic oxidation p-methoxytoluene 4-methoxybenzaldehyde dimethylacetal 4-methoxybenzaldehyde potassium fluoride |
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