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Asymmetric reactions with cyclodextrins
Authors:Keiko Takahashi  Kenjiro Hattori
Institution:(1) Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics, 243-02 Atsugi, Kanagawa, Japan
Abstract:Cyclodextrins have great potential for exploitation as a useful tool for asymmetric induction. Many kinds of asymmetric reaction have been achieved in the presence of cyclodextrin under various conditions such as the solid phase, heterogeneous suspension or homogeneous aqueous or organic solution. Complexation is essential for asymmetric induction. What is necessary to improve CDs for greater asymmetric induction?
Keywords:Cyclodextrin  asymmetric reaction  microcrystal
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