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Kinetics of the Oxidation of Fluoren-9-olsby 4-Nitro-1-chlorobenzotriazole |
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| Authors: | Ratinum Ulagi Perumal Kuselan Chockalingam Karunakaran |
| Affiliation: | (1) Department of Chemistry, LRG Government Arts College for Women, Tirupur-641604, India, IN;(2) Department of Chemistry, Presidency College, Chennai-600005, India, IN;(3) Department of Chemistry, Annamalai University, Annamalainagar-608002, India, IN |
| Abstract: | Summary. The oxidation of fluoren-9-ols by 4-nitro-1-chlorobenzotriazole in aqueous acetic acid is a second order reaction with a reaction constant of −1.4. The oxidation exhibits a kinetic deuterium isotope effect indicating the cleavage of the 9-C*H bond in the rate-determining step. The title oxidation is compared with that by 1-chlorobenzotriazole. Received October 23, 2000. Accepted (revised) January 22, 2001 |
| Keywords: | . Structure-reactivity relationship Reactivity-selectivity principle. |
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