| 钯催化Stille交叉偶联反应研究新进展 |
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| 引用本文： | 王德平,张旭东,梁云,李金恒. 钯催化Stille交叉偶联反应研究新进展[J]. 有机化学, 2006, 26(1): 19-26 |
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| 作者姓名： | 王德平 张旭东 梁云 李金恒 |
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| 作者单位： | 湖南师范大学化学化工学院,化学生物学与中药分析重点实验室,长沙,410081 |
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| 基金项目： | 国家自然科学基金(No.20202002)资助项目. |
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| 摘 要： | 综述了钯催化Stille交叉偶联反应的最新研究进展, 主要包括三个方面: (1)有机锡化合物与有机亲电试剂如卤代芳香烃、卤代烷烃、酰氯等的反应; (2)Stille反应的机理; (3) Stille反应在有机合成中的应用.
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| 关 键 词： | 钯 有机亲电试剂 Stille交叉偶联反应 有机锡化合物 |
| 收稿时间： | 2005-01-17 |
| 修稿时间： | 2005-05-24 |
Recent Progress in the Palladium-Catalyzed Stille Cross-Coupling Reactions |
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| WANG,De-Ping,ZHANG,Xu-Dong,LIANG,Yun,LI,Jin-Heng. Recent Progress in the Palladium-Catalyzed Stille Cross-Coupling Reactions[J]. Chinese Journal of Organic Chemistry, 2006, 26(1): 19-26 |
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| Authors: | WANG De-Ping ZHANG Xu-Dong LIANG Yun LI Jin-Heng |
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| Affiliation: | Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081 |
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| Abstract: | Recent development of the palladium-catalyzed Stille cross-coupling reactions is reviewed, which includes (1) the reactions of organotin compounds with organic electrophilic reagents such as aro-matic halides, alkyl halides, and acyl chlorides etc., (2) mechanisms of the palladium-catalyzed Stille reac-tion, and (3) the applications of the Stille reaction to organic synthesis. |
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| Keywords: | palladium electrophilic reagent Stille cross-coupling reaction organotin compound |
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