Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers |
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| Authors: | Garrison Jered C Panzner Matthew J Custer Paul D Reddy D Venkat Rinaldi Peter L Tessier Claire A Youngs Wiley J |
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| Institution: | Department of Chemistry, The University of Akron, Akron, OH 44325, USA. |
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| Abstract: | The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(III) and Pt(II) atoms occupying the vertices. |
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