Improved Electrochemistry in Low-Polarity Media Using Tetrakis(pentafluorophenyl)borate Salts as Supporting Electrolytes |
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| Authors: | LeSuer Geiger |
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| Institution: | Department of Chemistry University of Vermont Burlington, VT 05405 (USA). |
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| Abstract: | The noncoordinating anion B(C(6)F(5))(4)](-) solubilizes cations and polycations, allowing the generation and study of such systems in low-dielectric media. Thus, when NBu(4)]B(C(6)F(5))(4)] is used as a supporting electrolyte, cyclic voltammetry is possible in aliphatic ethers and other solvents of very low polarity. |
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