The Tetrakis(carbonyl)dioxoosmium(VI) Cation: trans- |
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Authors: | Bernhardt Willner Jonas Thiel Aubke |
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Institution: | San Diego Supercomputer Center MC 0505 9500 Gilman Drive, San Diego, CA 92093 (USA). |
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Abstract: | The first carbonyl compound of a transition metal in the oxidation state +6 was obtained by reductive carbonylation of OsO(4) in SbF(5). Through the use of extensive IR, NMR, and UV/Vis spectroscopic studies as well as density functional calculations it was determined that the trans-OsO(2)(CO)(4)](2+) cation adopts the octahedral structure shown in the picture with trans oxygen atoms. |
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