Synthesis and Structures of 1,3,5,7-Tetraazaheptatrienylsodium and -thallium(I) |
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| Authors: | Boesveld Hitchcock Lappert Nöth |
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| Affiliation: | The Chemistry Laboratory School of Chemistry, Physics and Environmental Science University of Sussex Brighton BN1 9QJ (UK). |
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| Abstract: | Highly stable multinuclear metal complexes with planar [{Me(3)SiNC(H)N}(2)CH](-) ligands are obtained from MN(SiMe(3))(2) (M=Na, Tl) and 1,3,5-triazine (structure for Tl shown in the picture). These complexes display unusual structural features such as a pseudo-C(3) symmetry (Na complex). |
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