An EPR Investigation of the Kinetics of Inclusion of a Persistent Radical in Water-Soluble Calix |
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| Authors: | Franchi Lucarini Pedulli Sciotto |
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| Institution: | Dipartimento di Chimica Organica "A. Mangini" Università di Bologna, Via S. Donato 15 40127 Bologna (Italy). |
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| Abstract: | Distinct EPR signals are observed for the free and included species for the inclusion of the neutral benzyl tert-butyl nitroxide probe into a calix4]arene host in water (shown schematically). Computer simulation of the EPR spectra recorded at various temperature enabled direct determination of the activation and kinetic parameters for this inclusion process. |
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