| 导电聚合物单体的光电聚合 |
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| 引用本文： | 陈衍珍,辜志俊,田中群. 导电聚合物单体的光电聚合[J]. 物理化学学报, 1993, 9(2): 277-280. DOI: 10.3866/PKU.WHXB19930226 |
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| 作者姓名： | 陈衍珍 辜志俊 田中群 |
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| 作者单位： | Department of Chemistry, Xiamen University, Xiamen 361005 |
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| 摘 要： | 苯胺、吡咯和噻吩等是重要的导电聚合物单体.光照可促进低聚物的形成,电化学技术可方便地实现单体的电聚合.目前,有关导电聚合物单体的光电聚合的报导还很少.本文研究征水溶液中、铂金属基底上,苯胺、吡咯和噻吩等单体的光电聚合过程.
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| 关 键 词： | 光电聚合 导电聚合物 聚苯胺 聚吡咯 聚噻吩 |
| 收稿时间： | 1992-02-10 |
| 修稿时间： | 1992-08-19 |
PHOTOELECTROCHEMICAL POLYMERIZATION OF CONDUCTING POLYMER MONOMERS |
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| Chen Yanzhen Gu Zhijun Tian Zhongqun. PHOTOELECTROCHEMICAL POLYMERIZATION OF CONDUCTING POLYMER MONOMERS[J]. Acta Physico-Chimica Sinica, 1993, 9(2): 277-280. DOI: 10.3866/PKU.WHXB19930226 |
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| Authors: | Chen Yanzhen Gu Zhijun Tian Zhongqun |
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| Affiliation: | Department of Chemistry, Xiamen University, Xiamen 361005 |
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| Abstract: | The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may be oxidized into polymerfilm. monomer→low polymer→polymerfilmIrradiation can accelerate the formation of low polymer. The rate of the first step for pyrrole and thiophene is slow, and the second step for aniline is slow. When the film is formed, it can speed up the rate of film formation. |
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| Keywords: | Photoelectrochemical polymerization Conducting polymer Polyaniline Polypurrole Polythiophene |
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