NiMo/Al_2O_3 catalyst containing nano-sized zeolite Y for deep hydrodesulfurization and hydrodenitrogenation of diesel |
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| Authors: | Hailiang Yin Tongna Zhou Yunqi Liu Yongming Chai Chenguang Liu State Key Laboratory of Heavy Oil Processing Key Laboratory of Catalysis CNPC China University of Petroleum Qingdao Sh ong China |
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| Affiliation: | Hailiang Yin,Tongna Zhou,Yunqi Liu,Yongming Chai,Chenguang Liu State Key Laboratory of Heavy Oil Processing,Key Laboratory of Catalysis,CNPC,China University of Petroleum,Qingdao 266555,Shandong,China |
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| Abstract: | Two mixed-matrix NiMo/Al2O3 catalysts containing nano-and micro-sized zeolite Y have been prepared to explore the size effect of zeolite Y particle on the hydrodesulfurization(HDS)and hydrodenitrogenation(HDN)activities of fluid catalytic cracking(FCC)diesel.They were characterized by SEM,BET,XRD,H2-TPR,NH3-TPD and HRTEM.The results show that the catalyst containing nano-sized zeolite Y possesses larger average pore diameter,higher pore volume,weaker and lesser acid sites,more easily reducible metal phases,... |
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| Keywords: | zeolite Y nano-sized zeolite micro-sized zeolite hydrodesulfurization hydrodenitrogenation diesel |
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