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Improved version of Doyle integral method for nonisothermal kinetics of solid-state reactions
Authors:Junmeng Cai  Ronghou Liu  Fei Shen
Affiliation:(1) Biomass Energy Engineering Research Center, School of Agriculture and Biology, Shanghai Jiao Tong University, 2678 Qixin Road, Shanghai, 201101, People’s Republic of China
Abstract:An improved version of Doyle integral method for the determination of the kinetic parameters from nonisothermal thermoanalytical data has been presented. The relative errors involved in the activation energy and frequency factor determined from Doyle integral method and its improved integral method have been estimated. The results have shown that the precision of the improved version of Doyle integral method for the determination the kinetic parameters (including the activation energy and frequency factor) is much higher than that of Doyle integral method.
Keywords:Doyle integral method  nonisothermal kinetics  kinetic parameter
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