Stability of rare-earth tetrafluorides |
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Authors: | Yu. M. Kiselev V. G. Sevast'yanov V. I. Spitsyn |
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Affiliation: | 1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow 2. M. V. Lomonosov Moscow State University, USSR
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Abstract: | 1. | According to thermogravimetric data, PrF4, decomposes when heated, with evolution of fluorine, as in the case of CeF4 and TbF4. | 2. | The authors have measured the vapor pressure of the fluorine formed by thermolysis of rare-earth tetrafluorides, and have calculated the thermodynamic characteristics of these tetrafluorides. |
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