Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes |
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Authors: | Murakami Masahiro Ishida Naoki Miura Tomoya |
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Institution: | Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan. murakami@sbchem.kyoto-u.ac.jp |
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Abstract: | Methylenecyclopropanes are carboxylated with gaseous carbon dioxide in the presence of a stoichiometric amount of a nickel complex; the reaction pathways are significantly influenced by the reaction solvent and the amine ligand. |
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