Inhibition and acceleration of deuterium exchange in amide-functionalized monolayer-protected gold clusters |
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Authors: | Briggs Cheryl Norsten Tyler B Rotello Vincent M |
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Affiliation: | Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA. |
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Abstract: | Hydrogen/deuterium exchange rates in amide-functionalized monolayer protected gold clusters (MPCs) are controlled by the radial nature of the surface, with inhibition and catalysis observed at different chain lengths. |
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