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Inhibition and acceleration of deuterium exchange in amide-functionalized monolayer-protected gold clusters
Authors:Briggs Cheryl  Norsten Tyler B  Rotello Vincent M
Affiliation:Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA.
Abstract:Hydrogen/deuterium exchange rates in amide-functionalized monolayer protected gold clusters (MPCs) are controlled by the radial nature of the surface, with inhibition and catalysis observed at different chain lengths.
Keywords:
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