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Clays basal spacings effect on fire retardancy of polymers by TG/DTA
Authors:Simone Pereira da Silva Ribeiro  Luciana Rocha de Moura Estev?o  Csaba Novák and Regina Sandra Veiga Nascimento
Institution:(1) Instituto de Qu?mica—DQO, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brazil;(2) Ag?ncia Nacional do Petr?leo, G?s Natural e Biocombust?veis—ANP, SCM, Rio de Janeiro, Brazil;(3) Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Budapest, Hungary
Abstract:In this study, poly (ethylene-co-butyl acrylate, EBA-30) samples containing an intumescent formulation of ammonium polyphosphate and pentaerythritol and clays of different basal spacings had their flame retardant properties evaluated by thermogravimetric analysis, differential thermal analysis, and heating microscopy. Samples without polymeric matrix were also analyzed to observe possible interactions between the clays and the intumescent formulation. Thermal Analyses revealed that the basal spacings of the clays strongly influence their synergistic effect with the intumescent formulation studied.
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