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Proton dipolar spin-lattice relaxation in hexagonal ice
Authors:R Blinc  H Gränicher  G Lahajnar  I Zupančič
Institution:(1) Swiss Federal Institute of Technology (ETH), CH-8049 Zürich, Hönggerberg, Switzerland;(2) Institute ldquoJ. Stefanrdquo, University of Ljubljana, Ljubljana, Yugoslavia
Abstract:The ultraslow motion of defects in high purity hexagonal H2O ice has been studied by proton dipolarT 1D measurements in the ldquostrong collisionrdquo limit, using the Jeener technique. The obtained NMR correlation times tau agree rather well with both the Schottky H2O diffusion timest s=langr 2rang/6D and the deuteron correlation times in D2O ice, suggesting that Schottky rather than interstitial diffusion dominates spin-lattice relaxation in both H2O and D2O ice.On leave of absence from University of Ljubljana, Institute ldquoJ. Stefanrdquo.
Keywords:
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