Structure and reactivity of an iodosylarene adduct of a manganese(IV)-salen complex |
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| Authors: | Wang Chunlan Kurahashi Takuya Fujii Hiroshi |
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| Affiliation: | Institute for Molecular Science, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787, Japan. |
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| Abstract: | O?transfer: The X-ray crystal structure of an iodosylarene adduct of a manganese(IV)-salen complex shows bis-iodosylarene coordination with a stepped conformation of the salen ligand. Spectroscopic characterization suggests that the complex maintains the same structure in solution. A reactivity study indicates that the manganese-bound iodosylarene can directly transfer an oxygen atom to substrate. |
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| Keywords: | bioinorganic chemistry high‐valent complexes iodosylarenes manganese oxygenation |
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