Crystal structure and magnetic properties of a Cs3Nb2I9 bioctahedral complex |
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| Authors: | S B Artemkina N G Naumov A V Virovets V A Daletskii S G Kozlova V E Fedorov |
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| Institution: | 12023. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
22023. Novosibirsk State Research University, Novosibirsk, Russia
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| Abstract: | A cluster complex Cs3Nb2I9 is obtained by a high-temperature reaction of niobium, iodine, and cesium iodide. Its crystal structure is determined: trigonal space group P63/mmc, a = 8.2463(3) Å, c = 19.5419(14) Å, V = 1150.84(10) Å3, R(F) = 0.0614. The compound obtained is characterized by temperature independent paramagnetism in the temperature range 70–290 K. |
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