Dimethyl dichloromalonate as a new synthetic equivalent of methyl dichloroacetate in the Darzens condensation |
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| Authors: | E A Berdnikov V A Mamedov |
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| Institution: | (1) V. I. Ul'yanov-Lenin Kazan'State University, 18 ul. Lenina, 420008 Kazan', Russian Federation;(2) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | Dimethyl dichloromalonate reacts with aldehydes in the presence of sodium methoxide to form -chloropyruvates,-chloroglycidates, or,-dichlorohydrins, depending on the nature of the aldehyde.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1544–1545, August, 1995. |
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| Keywords: | dimethyl dichloromalonate Darzens reaction  -chloroketones" target="_blank">gif" alt="agr" align="BASELINE" BORDER="0">-chloroketones -chloroepoxides " target="_blank">gif" alt="agr" align="BASELINE" BORDER="0"> -dichlorohydrins" target="_blank">gif" alt="agr" align="BASELINE" BORDER="0">-dichlorohydrins |
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