Synthesis and magnetic properties of wheel-shaped [Mn12] and [Fe6] complexes |
| |
| Authors: | Rumberger Evan M Zakharov Lev N Rheingold Arnold L Hendrickson David N |
| |
| Institution: | Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0358, USA. |
| |
| Abstract: | The reactions of the ligands N-methyldiethanol amine and N-ethyldiethanol amine (abbreviated H(2)mdea and H(2)edea, respectively) with Mn(12)O(12)(O(2)CCH(3))(16)(H(2)O)(4)] yield novel dodecanuclear wheel-shaped products. The capability of the ligands H(2)mdea and H(2)edea to support wheel structures in metals other than Mn is demonstrated with the crystal structure of a new hexanuclear ferric wheel. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
