| A NOVEL REACTION BETWEEN [μ-PhC(O)S]-(μ-RS)Fe_2(CO)_6 AND (μ-R~1S)(μ-XMgS)Fe_2(CO)_6——THE SYNTHESIS, CHARACTERIZATION AND FORMATION MECHANISM OF TWIN CLUSTER COMPLEXES [(μ-RS)Fe_2(CO)_6](μ_4-S)[(μ-R~1S)Fe_2(CO)_6] |
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| 引用本文： | 宋礼成,胡青眉,贾国锋,王劲扬.A NOVEL REACTION BETWEEN [μ-PhC(O)S]-(μ-RS)Fe_2(CO)_6 AND (μ-R~1S)(μ-XMgS)Fe_2(CO)_6——THE SYNTHESIS, CHARACTERIZATION AND FORMATION MECHANISM OF TWIN CLUSTER COMPLEXES [(μ-RS)Fe_2(CO)_6](μ_4-S)[(μ-R~1S)Fe_2(CO)_6][J].中国科学B辑(英文版),1992(1). |
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| 作者姓名： | 宋礼成 胡青眉 贾国锋 王劲扬 |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071，PRC，Department of Chemistry，Nankai University，Tianjin 300071，PRC，Department of Chemistry，Nankai University，Tianjin 300071，PRC，Department of Chemistry，Nankai University，Tianjin 300071，PRC |
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| 基金项目： | Project supported by the National Natural Science Foundation of China |
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| 摘 要： | The reaction of (μ-RS)(μ-XMgS)Fe_2(CO)_6 with PhC(O)Cl gave four new benzoyl complexes μ-PhC(O)S](μ-RS)Fe_2(CO)_6(R=Me, Et, n-Bu, CH_2=CHCH_2), which further reacted with (μ-R~1S)(μ-XMgS)Fe_2(CO)_6 to afford eight new twin cluster complexes with the general formula of (μ-RS)Fe_2(CO)_6](μ_4-S)(μ-R~1S)Fe_2(CO)_6]. The single crystal X-ray analysis for one of these complexes (R=n-Bu, R~1=Ph) showed that it consists of two different moieties PhSFe_2(CO)_6 and n-BuSFe_2(CO)_6 joined together through the spiran type of μ_4-S., The complex belongs to space group P-1; cell parameters are a=9.028(3), b=10.386(1), c=16.723 (5); α=87.70(2)°,β=75.67(2)°, r=82.26(2)°; z=2, Dx=1.743 g/cm~3. Final deviation factor R=0.031.
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