Highly Enantioselective Henry Reactions of Aromatic Aldehydes Catalyzed by an Amino Alcohol-Copper(II) Complex |
| |
| Authors: | Dan-Dan Qin Wen-Han Lai Di Hu Zheng Chen An-An Wu Yuan-Ping Ruan Zhao-Hui Zhou Hong-Bin Chen |
| |
| Institution: | Department of Chemistry and State Key Laboratory of Physical Chemistry for Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (P.R. China), Fax: (+86)?592-2185192. |
| |
| Abstract: | Amino alcohol-Cu(II) catalyst: Highly enantioselective Henry reactions between aromatic aldehydes and nitromethane have been developed. The reactions were catalyzed by an easily available and operationally simple amino alcohol-copper(II) catalyst. In total, 38 substrates were tested and the R-configured products were obtained in good yields with excellent enantioselectivities. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
