The
effect of Er(III) on the thermal behavior of azo (–N=N–) and azomethinic
(–CH=N–) chromophores |
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Authors: | Mihaela Badea R Olar A Emandi |
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Institution: | (1) Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, Bucharest, Romania, 050663 Sector 5, 90–92 Panduri St. |
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Abstract: | This paper reports the investigation of the thermal
stability of a series of new complexes with azo and azomethinic chromophores
of the type Er(HL)2(H2O)2](HO);
((B) H2L: o,o’-dihydroxy-azobenzene (A);
(D) H2L: N-(2-hydroxy-1-naphthalidene)aminophenol
(C); (F)
H2L: N-(2-hydroxy-1-naphthalidene)anthranilic acid
(E)). The complexes thermal behaviour steps
were investigated and comparatively presented with those of corresponding
ligand. The thermal transformations are complex processes according to TG
and DTG curves including phenol elimination, oxidative condensation and thermolysis
processes. The final product of complexes decomposition is Er2O3. |
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Keywords: | azo-derivatives azomethinic derivatives Er(III) complex thermal stability |
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