Uranium removal from aqueous solutions by wood powder and wheat straw |
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Authors: | Saeed Bagherifam Amir Lakzian Seyed Javad Ahmadi Mohammad Farhad Rahimi Akram Halajnia |
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Institution: | (1) Department of Soil Science, Faculty of Agriculture, Ferdowsi University of Mashhad, 91779 Mashhad, Iran;(2) Chemistry Research Group, Nuclear Science and Technology Research Institute, AEOI, Tehran, Iran;(3) Department of Nuclear Physics, Faculty of Science, Ferdowsi University of Mashhad, 91755 Mashhad, Iran |
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Abstract: | The influence of initial uranium concentration, solution pH, contact time and adsorbent mass was investigated for removal
of uranium from aqueous solutions by pine wood powder and wheat straw using a batch technique. The maximum removal efficiency
of uranium achieved at pH 8 and 7 for pine wood powder and wheat straw, respectively. Langmuir and Freundlich adsorption isotherms and three kinetic models of adsorption including; Elovich, Lagergren pseudo-first and Lagergren pseudo-second order were used to describe the adsorption mechanisms. The uranium sorption onto wood and wheat straw powders
followed a Freundlich isotherm. The kinetic studies showed that the data fitted very well to the pseudo-second order model in the studied concentration
range of uranium for both adsorbents. Uranium desorption from loaded adsorbents also studied using batch techniques as a function
of desorptive reagent, desorption time and desorptive reagent concentration. The results of the experiment indicated that
the optimum desorption efficiency of uranium for wood powder and wheat straw occurred in 5 min shaking time, using 1.5 M HNO3 and 2 M Na2CO3 solutions, respectively. |
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