Fusion entropy and melt viscosity in some aliphatic hydrocarbons. Relation between fusion entropy and parameterb of the Batchinski equation |
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Authors: | G Berchiesi |
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Institution: | (1) Istituto Chimico dell' Universitá, Via S. Agostino, 62032 Camerino, Italy |
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Abstract: | The fusion entropy, viscosity and molar volume are measured for the following hydrocarbons: C18H38, C19H40, C20H42 and C20H40. A relation between S
fus and the parameterb of the Batchinski equation is given for these compounds and for others previously studied. By employing the calorimetric and viscometric data found in the literature for ionic melts, a similar relation is found to hold for molten salts.
Zusammenfassung Die Schmelzentropie, die ViskositÄt und das Molvolumen wurden für folgende Kohlenwasserstoffe gemessen: C18H38, C19H40, C20H42, C20H40. Eine Korrelation zwischen Sfus und dem Parameterb der Gleichung von Batchinski wird für diese sowie für andere früher untersuchte Verbindungen vorgeschlagen. Durch Verwendung der kalorimetrischen und viskosimetrischen Literaturangaben für geschmolzene ionische Produkte wurde eine analoge Korrelation für geschmolzene Salze vorgeschlagen.
Résumé L'entropie de fusion, la viscosité et le volume molaire des hydrocarbures C18H38, C19H40, C20H42 et C20H40 ont été mesurés. Une relation entre l'entropie de fusion, Hfus, et le paramètreb de l'équation de Batchinski est proposée pour ces composés et pour d'autres, précédemment étudiés. En utilisant les données calorimétriques et viscosimétriques trouvées dans la littérature pour les produits ioniques fondus, une relation analogue est proposée pour les sels fondus.
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Thanks are due to the C.N.R. (Rome) for financial aid. |
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