Steroid total synthesis. 3. 9 , 10 -testosterone |
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Authors: | G Saucy R Borer |
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Abstract: | The total synthesis of 9β, 10α-testosterone via a BCD-tricyclic intermediate is described. The latter compound – 17β-hydroxy-des-A-androst-9-en-5-one – was obtained in optically active form by our previously reported scheme, using an efficient resolution step early in the synthesis. New results regarding the asymmetric induction step are also discussed. |
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