| 超声法合成新型3-(5-氯/苯氧基-3-甲基-1-苯基-4-吡唑基)异噁唑N-取代苯基去甲去氢斑蝥酰亚胺衍生物 |
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| 引用本文： | 贾兆祥,李燕萍,刘晨江.超声法合成新型3-(5-氯/苯氧基-3-甲基-1-苯基-4-吡唑基)异噁唑N-取代苯基去甲去氢斑蝥酰亚胺衍生物[J].有机化学,2006,26(3):375-378. |
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| 作者姓名： | 贾兆祥 李燕萍 刘晨江 |
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| 作者单位： | 新疆大学化学化工学院,乌鲁木齐,830046 |
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| 摘 要： | 去甲去氢斑蝥素与取代芳胺反应得到了一系列N-取代苯基去甲去氢斑蝥酰亚胺, 再与5-氯/苯氧基-4-(α-氯-α-肟基甲基)-3-甲基-1-苯基吡唑甲酰基氯代肟发生1,3-偶极环加成反应生成一系列未见报道的3-(5-氯/苯氧基-3-甲基-1-苯基-4-吡唑基)异噁唑N-取代苯基去甲去氢斑蝥酰亚胺衍生物. 所合成化合物经元素分析, IR, 1H NMR, 1H-1HCOSY, NOESY确证结构.
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| 关 键 词： | 去甲去氢斑蝥酰亚胺 1 3-偶极环加成 异噁唑 吡唑 超声波催化 |
| 收稿时间： | 03 15 2005 12:00AM |
| 修稿时间： | 09 13 2005 12:00AM |
Ultrasonic Synthesis of Novel 3-(5-Chloro/phenoxy-3-methyl-1- phenylpyrazo-4-yl)isoazolo-N-substituted phenyl-dehydronorcantharidimide Derivatives |
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| JIA,Zhao-Xiang,LI,Yan-Ping,LIU,Chen-Jiang.Ultrasonic Synthesis of Novel 3-(5-Chloro/phenoxy-3-methyl-1- phenylpyrazo-4-yl)isoazolo-N-substituted phenyl-dehydronorcantharidimide Derivatives[J].Chinese Journal of Organic Chemistry,2006,26(3):375-378. |
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| Authors: | JIA Zhao-Xiang LI Yan-Ping LIU Chen-Jiang |
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| Institution: | College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 |
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| Abstract: | Abstract A series of novel 3-(5-chloro/phenoxy-3-methyl-1-phenylpyrazo-4-yl)isoazolo-N-substituted phenyl-dehydronorcantharidimide derivatives were synthesized by the 1,3-dipolar cycloaddition reaction of 5-chloro/phenoxy-4-(α-chloro-α-oximidomethyl)-3-methyl-1-phenylpyrazole and N-substituted phenyldehydronorcantharidimide which was prepared by the reaction of dehydronor-cantharidin with substituted aniline. The structures of all compounds were confirmed by IR, 1H NMR, 1H-1HCOSY, NOESY spectra and elemental analysis. |
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| Keywords: | dehydronorcantharidimide 1 3-dipolar cycloaddition isoxazole pyrazole ultrasonic catalysis |
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