Biomimetic synthesis and structural revision of (+/-)-tridachiahydropyrone |
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| Authors: | Sharma Pallavi Griffiths Nicholas Moses John E |
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| Institution: | School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. |
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| Abstract: | A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data matched that of the isolated natural product, supporting a revised structure of this complex metabolite. |
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