Reactivity of the CCl3CH2CH2. radical in processes of homo-and cotelomerization of olefins with carbon tetrachloride

From the kinetic studies of CCl₃CH₂CH₂Br addition to 1-hexene, the rate constant of addition of the CCl₃CH₂CH ₂ ^. ( _e ¹ R) radical to 1-hexene 1g _e ¹ k_h=(5.2±0.1)–(13 000±800)/RT] has been determined. From the cotelomerization data, rate constants of the interaction of _e ¹ R-radical with ethylene 1g _e ¹ k_e=(6.1±0.2)–(21 400±1 200)/RT] and carbon tetrachloride 1g _e ¹ k_t=(7.5±0.2)–(37 000±1 200)/RT] have been calculated.

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CCl₃CH₂CH₂Br 1-. CCl₃CH₂CH ₂ ^. - _e ¹ R^.)- 1- (1g ¹ K=(5,2±0,1)–(13 000±800)/RT), 1- , ¹ R- (1g ¹ K=(6,1±0,2)–(21 400±1200/RT) CCl₄ (1g ¹ K=(7,5±0,2–(37 000±1 200)/RT).