On the kinetics and mechanism of Nb(V) hydrolysis |
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| Authors: | Ot vio L. Bottecchia,Julien F. C. Boodts |
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| Affiliation: | Otávio L. Bottecchia,Julien F. C. Boodts |
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| Abstract: | Kinetics of Nb(V) hydrolysis in MgCl2, Mg(ClO4)2 mixtures has been investigated by electroanalytical methods and the rate constants determined. A hydrolysis model based on species postulated in the literature is proposed. Resolution of the corresponding differential equations led to results consistent with experimental data obtained from polarographic current vs. time curves. © 1993 John Wiley & Sons, Inc. |
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