On the importance of specific solvent effects in electron trransfer reactions |
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Authors: | María Luisa Moy Francisco Snchez John Burgess |
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Institution: | María Luisa Moyá,Francisco Sánchez,John Burgess |
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Abstract: | The intramolecular electron transfer reaction within the binuclear complex formed between tetraamminepyrazinecarboxylatocobalt(III) and aquopentacyanoferrate(II) ions is studied in various binary aqueous media at different temperatures. Results could not be explained on the basis of a primitive model. Experimental data were fitted by using a multiparameter regression which shows the important role played by specific interactions on reactivity. © 1993 John Wiley & Sons, Inc. |
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