|
|||||
|
|
Kinetics of radical polymerization of dimethylphenyl methacrylates |
|
| Authors: | Ljubica Vrhovac Nebojs&#x;a Djurasovi&#x; Jovan veli kovi&#x; |
| Institution: | Ljubica Vrhovac,Nebojs̃a Djurasović,Jovan veličković |
| Abstract: | The kinetics of free radical polymerization of all six existing isomeric dimethylphenyl methacrylates were studied in bulk at 60°C, initiated by dilauroyl peroxide, using dilatometry. The different polymerization rates observed, resulting from the different monomer structures, are discussed in terms of steric and other effects, considering also the previous results for tolyl methacrylates. © 1993 John Wiley & Sons, Inc. |
| Keywords: | free radical polymerization dimethylphenyl methacrylates kinetics dilatometry dipoles interaction |