Abstract: | Direct reaction of iron pentacarbonyl with 1-N,N-disubstituted-cyclohexa-2,5-dicnecarboxamide and 1-N,N-disubstituted-cyclohexa-1,3-dienecarboxamide mixture (in which the disubstkuted group is diethyl or diphenyl) gave the isomeric tricarbonyl iron complexes of 2-N,N-disubstituted-1,4-η-cyclohexa-1,3-dienccarboxamide (1), 1-N,N-disubslituted-1,4-η-cyclohexa-1,3-dienecarboxamide (2), and 5-N,N-disubstituted-1,4-η-cyclohexa-1,3-dienecarboxamide (3) and tricarbonyliron complexes of l-N,N-disubstituted-cyclohexenecarboxamide (4). These complexes were separated and characterized by IR, UV-VIS, 1H NMR, elemental analysis, and mass spectra. Only 1 isomerized to give 2 under acidic conditions; both 1 and 2 undergo hydride abstraction with triphenylmethyl hexafluorophosphatc. Complexes 3, undergo neither isomcrization nor hydride abstraction. According to the spectral data, the possible interaction between carboxamide and iron carbonyl moiety was investigated. The irreversible electrochemical behavior of these complexes were studied. |