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Synthesis and Cyclization of Sulfur-Substituted Azido Dienes to Pyrrolizidine and Indolizidine Moieties
Authors:Shang-Shing P. Chou  Hung-Juan Tsao  Chien-Ming Lee  Chung-Ming Sun
Abstract:Sulfur-substituted azido dienes 1 and 11 , conveniently prepared from the corresponding 3-sulfolenes 5 and 10 , were thermolyzed to give pyrrolizidine and indolizidine products, 6 , 7 and 14 .
Keywords:Azides  Dienes  1,3-Dipolar cycloaddition  3-Sulfolenes  Sulfur-substituted dicnes  Pyrrolizidines  Indolizidines
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