| One—dimesional Infinite Chain Organotin Compounds： Synthesis and structural Characterization of Triphenyltin Thiazole—2—carboxylate and Triphenyltin 3—Pyridinylcarboxylate |
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| 引用本文： | 尹汉东,王传华,马春林,王勇.One—dimesional Infinite Chain Organotin Compounds： Synthesis and structural Characterization of Triphenyltin Thiazole—2—carboxylate and Triphenyltin 3—Pyridinylcarboxylate[J].中国化学,2002,20(10):1129-1133. |
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| 作者姓名： | 尹汉东 王传华 马春林 王勇 |
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| 作者单位： | DepartmentofChemistry,LiaochengUniversity,Liaocheng,Shandong252059,china |
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| 摘 要： | Triphenyitin thiazole-2-carboxylate(1) and triphenyltin 3-pyridinylcar boxylate(2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X-ray diffraction analysis.In the structure of 1, the tin atom is five-coordinated in a distorted trigonal bipyramidal structure.Due to the presence of a close intermolecular Sn…S interaction distance of 0.3666nm,the structre can be described as a weakly-bridged on-dimensional chain compound.In the structure of 2,the tin atom is five-coordinated with bridging 3-pyridinylcarboxylate ligands N atom and resulting structure is one-dimensional chain compound.
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| 关 键 词： | 噻唑－2－羧酸酯 三苯基锡 3－吡啶基羧酸酯 链式复合物 合成 晶体结构 |
One‐dimensional Infinite Chain Organotin Compounds: Synthesis and Structural Characterization of Triphenyltin Thiazole‐2‐carboxylate and Triphenyltin 3‐Pyridinylcarboxylate |
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| Han‐Dong Yin,Chuan‐Hua Wang,Chun‐Lin Ma,Yong Wang.One‐dimensional Infinite Chain Organotin Compounds: Synthesis and Structural Characterization of Triphenyltin Thiazole‐2‐carboxylate and Triphenyltin 3‐Pyridinylcarboxylate[J].Chinese Journal of Chemistry,2002,20(10):1129-1133. |
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| Authors: | Han‐Dong Yin Chuan‐Hua Wang Chun‐Lin Ma Yong Wang |
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| Abstract: | Triphenyltin thiazole‐2‐carboxylate (1) and triphenyltin 3‐pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole‐2‐carboxylate or sodium 3‐pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X‐ray diffraction analysis. In the structure of 1, the tin atom is five‐coordinated in a distorted trigonal bipyramidal structure. Due to the presence of a close intermolecular Sn…S interaction distance of 0.3666 nm, the structure can be described as a weakly‐bridged one‐dimensional chain compound. In the structure of 2, the tin atom is five‐coordinated with bridging 3‐pyridinylcarboxylate ligands N atom and resulting structure is one‐dimensional chain compound. |
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| Keywords: | triphenyltin thiazole‐2‐carboxylate 3‐pyridinylcarboxylate one‐dimensional chain compound crystal structure |
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