Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis |
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| Authors: | Kulkarni Amol A Diver Steven T |
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| Affiliation: | Department of Chemistry, University at Buffalo, the State University of New York, Amherst, New York 14260, USA. |
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| Abstract: | [reaction: see text] The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne. |
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