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Nucleophilic identity substitution reactions. The reaction between ammonia and protonated amines
Authors:Laerdahl Jon K  Bache-Andreassen Lihn  Uggerud Einar
Affiliation:Department of Chemistry, University of Oslo, PO Box 1033, Blindern, N-0315 Oslo, Norway.
Abstract:The gas phase reactions between NH3 and the protonated amines MeNH3+, EtNH3+, PriNH3+, and Bu(t)nH3+ have been studied by high level ab initio methods. Mass spectrometric experiments yielded no significant reaction products; this result being consistent with the calculated reaction barriers. The potential energy profiles for both nucleophilic substitution (SN2) and elimination (E2) pathways have been investigated. Both back side Walden inversion (SNB) and front side (SNF) nucleophilic reaction profiles have been generated. The SNB reaction barriers are found to be higher for the more alkyl substituted reaction centres. Reaction barrier trends have been analysed and compared with the results of a similar study of the H2O-ROH2+ system (R = Me, Et, Pri, and Bu(t)).
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