Bridgehead arylation: a direct route to advanced intermediates for the synthesis of C-20 diterpene alkaloids |
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| Authors: | Williams Craig M Mander Lewis N |
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| Institution: | Chemistry Department, School of Molecular and Microbial Sciences, University of Queensland, St. Lucia, 4072, Queensland, Australia. c.williams3@mailboz.uq.edu.au |
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| Abstract: | reaction: see text] Rapid access to the ABCE ring system of the C(20) diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo3.3.1]nonane derivative. |
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