Synthesis of heterocyclic and carbocyclic fluoro-olefins by ring-closing metathesis |
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Authors: | Salim Sofia S Bellingham Richard K Satcharoen Vachiraporn Brown Richard C D |
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Institution: | Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, U.K. |
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Abstract: | reaction: see text] Ring-closing metathesis (RCM) of vinyl fluoride-containing dienes in the presence of ruthenium alkylidene carbene complex 11 proceeded efficiently to give six- and seven-membered cyclic vinyl fluorides. The RCM reaction was used to prepare amine- and sulfamide-linked cyclo-olefins, as well as carbocyclic systems, from a simple commercial fluoro-olefin. |
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